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Conference publicationsIR-spectra of water clusters and dumping of the fluctuations of atomic groups in water environmentRussia, Moscow We consider transformation of vibrational IR-spectrum of water owing to formation of clusters from a small number of molecules H2O. Also an influence of H-bonds on rotational spectrum of water is considered. By means of molecular dynamics we analyze the problem of the dumping of atomic group fluctuations in water environment. It is shown that these fluctuations are not overdumped as it is predicted by Stokes theory. |
